Surface Modification of Polypropylene by Photografting of Vinyl Acetate Monomers

Authors

  • J. Balart Polytechnic University of Valencia, Spain
  • J.M. Espana Polytechnic University of Valencia, Spain
  • D. Garcia-Sanoguera Polytechnic University of Valencia, Spain
  • L. Sanchez-Nacher Polytechnic University of Valencia, Spain
  • T. Boronat Polytechnic University of Valencia, Spain

Keywords:

photopolymerization, vinyl acetate, adhesion, polypropylene

Abstract

The consumption of polymeric materials has increased in recent years. Among the wide variety of polymers, polyolefins are the most used at an industrial level. They have an optimal balance between processing and final properties, being used in low-technology sectors. There are some high-technology sectors that require prior surface modification of polyolefins to improve the mechanical properties of adhesive joints. With this modification, the surface free energy is increased. The aim of this work was to modify the surface of polypropylene using the photopolymerization treatment. The surface free energy has an increase of 175%, while the T-peel force has been increased by 700%.

Author Biographies

J. Balart, Polytechnic University of Valencia, Spain

Materials Technology Institute (ITM)

J.M. Espana, Polytechnic University of Valencia, Spain

Materials Technology Institute (ITM)

D. Garcia-Sanoguera, Polytechnic University of Valencia, Spain

Materials Technology Institute (ITM)

L. Sanchez-Nacher, Polytechnic University of Valencia, Spain

Materials Technology Institute (ITM)

T. Boronat, Polytechnic University of Valencia, Spain

Materials Technology Institute (ITM)

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Published

2011-07-09

Issue

Section

MATERIALS SCIENCE AND ENGINEERING